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91.
高强度聚焦超声(HIFU)是一种无创的热消融疗法,为保证其安全性和有效性,需要一种精度高、速度快的测温方法在其治疗过程中对温度进行监控.基于质子共振频率位移(PRFS)的磁共振温度成像(MRT)对温度具有较高的灵敏度,且与温度具有良好的线性关系,因此常被用于引导HIFU治疗.然而在实际应用中,HIFU治疗的最大隐患在于可能造成表皮灼伤,并且灼伤区域可能与焦点区域相隔较远.因此MRT的监控范围十分重要.本文基于三维回波平移成像序列,结合可控混叠的空间并行成像技术,实现了时间分辨率为3 s的快速三维温度成像.为了验证该方法的精度,本文首先设计了仿体降温实验,利用光纤温度计验证回波平移序列测温的准确度和精确度.然后在室温条件下扫描离体猪肉组织,对比加速前后的MRT的测温精确度.在HIFU加热条件下扫描离体猪肉组织,对比加速前后的MRT的测温准确度.结果显示,本文提出的方法可以在3 s内完成三维温度精准测量,对于HIFU治疗的安全监控具有重要意义. 相似文献
92.
Mahmoud Nasrollahzadeh Mohaddeseh Sajjadi Hartmut Komber Hossein Ali Khonakdar S. Mohammad Sajadi 《应用有机金属化学》2019,33(7)
In the present work, for the first time we have designed a novel approach for the synthesis of N‐benzyl‐N‐aryl‐5‐amino‐1H‐tetrazoles using reduced graphene oxide (rGO) decorated with Cu‐Ni bimetallic nanoparticles (NPs). In situ synthesis of Cu/Ni/rGO nanocomposite was performed by a cost efficient, surfactant‐free and environmentally benign method using Crataegus azarolus var. aronia L. leaf extract as a stabilizing and reducing agent. Phytochemicals present in the extract can be used to reduce Cu2+ and Ni2+ ions and GO to Cu NPs, Ni NPs and rGO, respectively. Analyses by means of FT‐IR, UV–Vis, EDS, TEM, FESEM, XRD and elemental mapping confirmed the Cu/Ni/rGO formation and also FT‐IR, NMR, and mass spectroscopy as well as elemental analysis were used to characterize the tetrazoles. The Cu/Ni/rGO nanocomposite showed the superior catalytic activity for the synthesis of N‐benzyl‐N‐aryl‐5‐amino‐1H‐tetrazoles within a short reaction time and high yields. Furthermore, this protocol eliminates the need to handle HN3. 相似文献
93.
94.
Johisner Penagos‐Llanos Olimpo García‐Beltrn J. A. Caldern Edgar Nagles J. J. Hurtado 《Electroanalysis》2019,31(4):695-703
The detection of Allura red (AR) by electrochemical reduction using a different electrode from the conventional mercury electrode is presented. A carbon paste with cobalt (II, III) oxide composite electrode (CoOx/CPE) is reported for the first time for the detection of AR. Moreover, others dyes such as tartrazine (TZ), sunset yellow (SY), amaranth (AM), Ponceaut 4‐R (P‐4R), and Sudan (SD) as well as pharmaceutical agents such as paracetamol (PMC) that are present in samples that contained AR did not show a reduced signal between 0.0 and ?0.3 V, which is the potential range where AR reduction was observed. The surface electroactivity was studied using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM). The presence of CoOX increased the cathodic peak current for AR by more than 50 % and 65 % via CV and square wave voltammetry (SWV), respectively, compared with an unmodified carbon paste electrode. Under the optimal parameters, (pH=3.0, accumulation time (tACC)=60 s and accumulation potential (EACC)=0.50 V), the detection limit for AR was 0.05 μmol L?1. The new sensor was sensitive and stable for the detection of AR. Moreover, it was easily manufactured and very convenient for food samples such as soft and isotonic drinks as well as chili sauce. 相似文献
95.
In 1994, I. Kan constructed a smooth map on the annulus admitting two physical measures, whose basins are intermingled. In this paper, we prove that Kan's map is robustly topologically mixing. 相似文献
96.
In this work we obtain positive singular solutions of where is a sufficiently small perturbation of the cone where has a smooth nonempty boundary and where satisfies suitable conditions. By singular solution we mean the solution is singular at the ‘vertex of the perturbed cone’. We also consider some other perturbations of the equation on the unperturbed cone Ω and here we use a different class of function spaces. 相似文献
97.
98.
Motivated by recent progress in dynamical sampling we prove that every frame which is norm-bounded below can be represented as a finite union of sequences for some bounded operators and elements in the underlying Hilbert space. The result is optimal, in the sense that it turns out to be problematic to replace the collection of generators by a singleton: indeed, for linearly independent frames we prove that we can represent the frame in terms of just one system , but unfortunately this representation often forces the operator T to be unbounded. Several examples illustrate the connection of the results to typical frames like Gabor frames and wavelet frames, as well as generic constructions in arbitrary separable Hilbert spaces. 相似文献
99.
100.